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Open-chain molecules may have different conformations; rotation around single bonds shifts several bands. As a consequence, the observed spectra exhibit relatively broad bands resulting from overlapping of the spectra of the conformational isomers. In ring systems, on the other hand, free rotation is largely inhibited or at least limited. The resulting IR and Raman spectra thus show very narrow bands. The number of bands increases as the size of the molecules increases and the symmetry is reduced (Figs. 4.1-9, 4.1-13, 4.1-19). Raman spectra of saturated unsubstituted carbocycles exhibit not only bands which are typical of CH2 groups, but also bands representing characteristic in-phase vibrations of C-C bonds: cyclopropane at 1188 cm-' (Fig. 4.1-10), cyclobutane at 1001 cm I , cyclopentane at 886 cm-', and cyclohexane at 802 cm I . These vibrations are also found in many substituted ring systems: C3 between 1220 and 1200 cm I , Cd between 930 and 850 cm C5 between 810 and 800 cm and C6 between 800 and 700 cm I.

In Baxall it was explained that whether a defect is latent is determined by reference to the inadequacy of the work or materials: The concept of a latent defect is not a dif cult one It means a concealed aw What is a aw It is the actual defect in the workmanship or design But when is a concealed aw in workmanship or design (and for that matter materials) to be regarded as observable even though not actually observed Sanderson con rms that answering this question is an exercise that must be approached objectively For example, in Riverstone Meat Pty Ltd v Lancashire Shipping Company Ltd (1961) a case that concerned the carriage of goods by sea it was decided that defects were not latent if discoverable by the exercise of due diligence Similarly, in Prudent Tankers Ltd SA v.

The key distinction between simple contracts and specialties, at least for the purposes of defects, is the resultant limitation period. For simple contracts the limitation period is 6 years from accrual of the cause of action, whereas for specialties it is 12 years (unless, in either case, the contract expressly provides otherwise). After the expiry of the relevant limitation period the right to bring a claim under the contract is barred. It is important to note, however, that the expiry of the limitation period bars the remedy, not the right. This means that a cause of action that has become statute-barred may not be used as the basis of a claim, but it may be set up as a defence to a claim (to the extent that it would, but for the expiry of the limitation period, have constituted a defence: see Filross Securities Ltd v. Midgeley (1988)).

Natural language processing programs have been applied in several areas. The most important are human-to-computer interfaces, which include abstracting and summarizing text, analyzing grammar, understanding speech, and even composing letters by machines. These programs translate one natural language to another, or one computer language to another, and they even translate Web pages (see 4). By far the most dominant use of NLP is front-ends for other software packages, especially databases that allow the user to operate the applications programs with everyday language.

A:PE1# configure router mpls lsp 118-116 A:PE1>config>router>mpls>lsp# info ----------------------------------------to 10.0.0.116 cspf fast-reroute facility exit metric 100 primary "loose" exit no shutdown -----------------------------------------

The Dominion Insurance Co Ltd (The Caribbean Sea) (1981) a case that concerned the terms of a marine insurance policy the same conclusion was reached Subsequently, in Rotherham MBC v Frank Haslam Milan & Co Ltd and M J Gleeson (Northern) Ltd (1996) a building case concerning the suitability of materials the term latent defect was described as meaning in its widest sense a failure in work or materials to conform to contract in a respect not apparent on reasonable examination In this case it was not appreciated by the speci er or builder at.

Introduction / 91 Design of a Radiotracer Experiment / 92 4.2.1 Basic Design Criteria / 92 4.2.2 Practical Considerations / 95 Preparation of Radiotracers and Their Compounds / 97 4.3.1 Chemical Synthesis / 99 4.3.2 Biosynthesis / 100 4.3.3 Tritium Labeling / 100 4.3.4 Radiolysis of Labeled Compounds / 101

instead of just giving you instructions, support, and a gentle push, you ll soon have to call him every time you want to get anywhere. Even worse, if you feel stif led by this experience, you might not ask for help the next time you need it to preserve your latitude. Ask your boss:

for a smaller organization such as a start-up company, inevitably there is lots of pressure to get things out the door quickly. Things are often very focused. Whether large or small, however, I think one of the hardest things I have found in working for corporate research is learning to work with the development